@jtronicus may have a lot more information based on your answers, but here are some support articles that may help you. The first one is how to get all of the features into Home Assistant for our devices. You may have already done this and the article does not cover all of the many Home Assistant setups.
The next article is a brief overview of how to setup automations in the HA GUI based on the scene events created by our switches (double, triple press etc.). I am not sure how to control Philips Hue in HA as I haven’t ever done that, but the steps should be similar. Just different info for the “Actions” section.